First example of benzothiazole azo dyes containing cyclopentadienyliron polynorbornene macromolecules

被引：18

作者：

Abd-El-Aziz, AS ^{[1
]}

Okasha, RM ^{[1
]}

Afifi, TH ^{[1
]}

机构：

[1] Univ Winnipeg, Dept Chem, Winnipeg, MB R3B 2E9, Canada

来源：

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2004年 / 14卷 / 04期

关键词：

organoiron polynorbornenes; ring opening metathesis polymerization; bis(tricyclohexylphosphine)benzylideneruthenium(IV) dichloride (Grubbs' catalyst); COSY-NMR;

D O I：

10.1023/B:JOIP.0000048031.82464.ac

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 [高分子化学与物理]; 080501 [材料物理与化学]; 081704 [应用化学];

摘要：

Soluble cationic organoiron polynorbornenes with pendent hetarylazo side chains have been synthesized via ring opening metathesis polymerization (ROMP) using bis(tricyclohexylphosphine)benzylideneruthenium(IV) dichloride (Grubbs' catalyst). The vibrantly colored organoiron polymers displayed weight average molecular weights between 24500 and 40900 and exhibited glass transition temperatures at 146degreesC and 161degreesC.

引用

页码：269 / 278

页数：10

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