Local Co structure in epitaxial CoxTi1-xO2-x anatase -: art. no. 100401

被引：105

作者：

Chambers, SA ^{[1
]}

Heald, SM ^{[1
]}

Droubay, T ^{[1
]}

机构：

[1] Pacific NW Natl Lab, Fundamental Sci Div, Richland, WA 99352 USA

来源：

PHYSICAL REVIEW B | 2003年 / 67卷 / 10期

关键词：

D O I：

10.1103/PhysRevB.67.100401

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We have used Co K-shell near-edge and extended x-ray absorption fine structure to investigate the charge state and local structure surrounding Co in epitaxial Co-doped TiO2 anatase grown on LaAlO3(001). Co is in the +2 formal oxidation state throughout the film, and substitutes for Ti in the lattice, creating a nearby oxygen vacancy in the process. There is no evidence for either elemental Co or CoO in the films.

引用

页数：4

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