Effect of solvent polarity on the aggregation of C60

被引：82

作者：

Nath, S ^{[1
]}

Pal, H ^{[1
]}

Sapre, AV ^{[1
]}

机构：

[1] Bhabha Atom Res Ctr, Radiat Chem & Chem Dynam Div, Chem Grp, Bombay 400085, Maharashtra, India

来源：

CHEMICAL PHYSICS LETTERS | 2000年 / 327卷 / 3-4期

关键词：

D O I：

10.1016/S0009-2614(00)00863-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

C-60 forms aggregates in solution when the dielectric constant of the solvents exceeds some critical value viz. greater than or equal to 13. Further, for aggregation the C-60 concentration has to exceed some critical value. The aggregation process is reversible and the aggregates exist in equilibrium with monomers. Picosecond laser flash photolysis experiments indicate that the excited (S-1) aggregates undergo very fast relaxation without contributing towards the tripler formation. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：143 / 148

页数：6

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