Resolution of hydrocarbons by inclusion complexation with a chiral host compound

被引：13

作者：

Miyamoto, H

Sakamoto, M

Yoshioka, K

Takaoka, R

Toda, F ^{[1
]}

机构：

[1] Okayama Univ Sci, Fac Sci, Dept Chem, Okayama 7000005, Japan

[2] Ehime Univ, Fac Engn, Dept Appl Chem, Matsuyama, Ehime 7908577, Japan

来源：

TETRAHEDRON-ASYMMETRY | 2000年 / 11卷 / 15期

关键词：

D O I：

10.1016/S0957-4166(00)00269-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Some racemic unsaturated hydrocarbons, 3- and 4-methyl and 4-vinylcyclohexene, bicyclo[4.3]nonane-2,5-diene, and 3-chloro- and 3,4-dichloro-1-butene were resolved as inclusion complex crystals with a chiral host compound derived from tartaric acid. The inclusion complexation, purified by repeating recrystallization from ether twice and decomposed by heating in vacuo, gave optically active hydrocarbons of 28-75% ee by distillation. The optical resolution by inclusion complexation in a water suspension medium and by fractional distillation in the presence of a chiral host was also applied to these hydrocarbons. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：3045 / 3048

页数：4

共 12 条

[1] FORMATION AND THERMAL REARRANGEMENTS OF SOME DIMERS OF BUTADIENE AND PIPERYLENE - TESTS OF VALIDITY OF THERMOCHEMICAL-KINETIC ARGUMENTS FOR IDENTIFICATION OF COMMON BIRADICAL INTERMEDIATES [J].