Role of CsF on electron injection into a conjugated polymer

被引:152
作者
Piromreun, P
Oh, H
Shen, YL
Malliaras, GG [1 ]
Scott, JC
Brock, PJ
机构
[1] Cornell Univ, Dept Mat Sci & Engn, Ithaca, NY 14853 USA
[2] IBM Corp, Almaden Res Ctr, Div Res, San Jose, CA 95120 USA
关键词
D O I
10.1063/1.1317547
中图分类号
O59 [应用物理学];
学科分类号
摘要
We studied electron injection from Al and Au cathodes into the conjugated polymer poly[2-methoxy,5-(2-ethylhexoxy)-1,4-phenylene vinylene] (MEH-PPV). When a thin CsF layer is inserted between MEH-PPV and Al, a substantial enhancement in electron injection is observed. Insertion of the same layer between MEH-PPV and Au does not have a similar effect, indicating that the enhancement mechanism is specific to CsF and Al. Thin Cs layers enhance electron injection regardless of the cathode metal. A mechanism that explains these observations is proposed. (C) 2000 American Institute of Physics. [S0003-6951(00)04341-2].
引用
收藏
页码:2403 / 2405
页数:3
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