Hydrothermal evolution of the thiourea-cerium(III) nitrate system: Formation of cerium hydroxycarbonate and hydroxysulfate

被引：24

作者：

Han, ZH

Qian, YT ^{[1
]}

Yu, SH

Tang, KB

Zhao, HQ

Guo, N

机构：

[1] Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China

[2] Univ Sci & Technol China, Struct Res Lab, Hefei 230026, Peoples R China

来源：

INORGANIC CHEMISTRY | 2000年 / 39卷 / 19期

关键词：

D O I：

10.1021/ic0001309

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Through the examination of solutions by Raman spectroscopy and the characterization of solid products by XRD, XPS, and FT-IR spectroscopy, the hydrothermal evolution of the thioure-acerium nitrate system was investigated. Thiourea decomposes before the formation of orthorhombic CeOHCO3. Monoclinic CeOHSO4 is produced after SO42- is derived from NO3- and HS- in the solution at higher temperatures. PL spectra show that the new phase has a photoluminescence intensity that is about 400 times that of CeOHCO3.

引用

页码：4380 / 4382

页数：3

共 17 条

[1] Raman spectra of amino acids and related compounds II Guanidine and urea derivatives [J].