A novel heterobimetallic Ni(II)-Ag(I) cyano-bridged coordination polymer incorporating Ag•••Ag interactions:: {[Ni(cyclen)][Ag(CN)2]}[Ag(CN)2]

被引：23

作者：

Shek, IPY

Wong, WY

Lau, TC

机构：

[1] City Univ Hong Kong, Dept Biol & Chem, Hong Kong, Hong Kong, Peoples R China

[2] Hong Kong Baptist Univ, Dept Chem, Kowloon Tong, Peoples R China

来源：

NEW JOURNAL OF CHEMISTRY | 2000年 / 24卷 / 10期

关键词：

D O I：

10.1039/b004939p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of nickel(II) acetate with cyclen (cyclen = 1,4,7,10-tetraazacyclododecane) and K[Ag(CN)(2)] gave {[Ni(cyclen)]-[Ag(CN)(2)] [Ag(CN)(2)], which consists of cis-[Ni(cyclen)(2+) units bridged by [Ag(CN)(2)](-) to form a zig-zag chain; the Ag atoms of the free and bridging [Ag(CN)(2)](-) also align together to form an infinite zig-zag chain with short Ag ... Ag distances.

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页码：733 / 734

页数：2

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