Photolysis of an alkoxyamine using intramolecular energy transfer from a quinoline antenna - towards photo-induced living radical polymerization

被引：64

作者：

Goto, Atsushi ^{[1
]}

Scaiano, J. C.

Maretti, Luca

机构：

[1] Kyoto Univ, Inst Chem Res, Kyoto 6110011, Japan

[2] Univ Ottawa, Dept Chem, Ottawa, ON K1N 6N5, Canada

来源：

PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES | 2007年 / 6卷 / 08期

关键词：

D O I：

10.1039/b705671k

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The photolysis of an alkoxyamine triad comprised of the 1-phenylethyl moiety, 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO) and 2-methyl-3-hydroxy quinoline leads to energy transfer from the quinoline moiety (antenna) and cleavage of the C-O alkoxyamine bond, suggesting its possible applications in low temperature living free radical polymerization.

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收藏

页码：833 / 835

页数：3

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