Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by C-H Bond Cleavage

被引：2504

作者：

Ackermann, Lutz ^{[1
]}

Vicente, Ruben ^{[1
]}

Kapdi, Anant R. ^{[1
]}

机构：

[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 52期

关键词：

arylation; biaryls; C-H functionalization; homogeneous catalysis; transition metals; CROSS-COUPLING REACTIONS; INTRAMOLECULAR DIRECT ARYLATION; DIRECT C-2 ARYLATION; INCLUDING FREE (NH)-IMIDAZOLE; PROTON-ABSTRACTION MECHANISM; PALLADIUM-PROMOTED SYNTHESIS; MEDIATED DIRECT ARYLATION; ONE-POT SYNTHESIS; ARYL CHLORIDES; REGIOSELECTIVE ARYLATION;

D O I：

10.1002/anie.200902996

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(figure represented) Cutting across: Direct arylations are increasingly viable alternatives to conventional cross-coupling reactions with stoichiometric amounts of organometallic reagents (see Scheme). This Review summarizes recent progress in the rapidly evolving research area of transition-metalcatalyzed C-H bond-cleavage reactions for (hetero)aryl syntheses. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：9792 / 9826

页数：35

共 414 条

[1] Catalytic arylation reactions by C-H bond activation with aryl tosylates
Ackermann, L
Althammer, A
Born, R
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (16) : 2619 - 2622
[2] Air-stable phosphine oxides as preligands for catalytic activation reactions of C-Cl, C-F, and C-H bonds
Ackermann, L
Born, R
Spatz, JH
Althammer, A
Gschrei, CJ
[J]. PURE AND APPLIED CHEMISTRY, 2006, 78 (02) : 209 - 214
[3] Cross-coupling reactions of aryl and vinyl chlorides catalyzed by a palladium complex derived from an air-stable H-phosphonate
Ackermann, L
Gschrei, CJ
Althammer, A
Riederer, M
[J]. CHEMICAL COMMUNICATIONS, 2006, (13) : 1419 - 1421
[4] Efficient aryl-(hetero)aryl coupling by activation of C-Cl and C-F bonds using nickel complexes of air-stable phosphine oxides
Ackermann, L
Born, R
Spatz, JH
Meyer, D
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (44) : 7216 - 7219
[5] Ackermann L, 2009, MODERN ARYLATION METHODS, P1
[6] Phosphine oxides as preligands in ruthenium-catalyzed arylations via C-H bond functionalization using aryl chlorides
Ackermann, L
[J]. ORGANIC LETTERS, 2005, 7 (14) : 3123 - 3125
[7] Modular diamino- and dioxophosphine oxides and chlorides as ligands for transition-metal-catalyzed C-C and C-N couplings with aryl chlorides
Ackermann, L
Born, R
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (16) : 2444 - 2447
[8] Ackermann L., 2007, ANGEW CHEM, V119, P6482
[9] Ackermann L., 2005, Angew. Chem, V117, P2497
[10] Ackermann L., 2006, Angew. Chem, V118, P7789

← 1 2 3 4 5 6 7 8 9 10 →