Scaling of dynamics in 2d semi-dilute polymer solutions

被引:23
作者
Cicuta, P
Hopkinson, I
机构
[1] Univ Cambridge, Cavendish Lab, Cambridge CB3 0HE, England
[2] Univ Manchester, Dept Phys, Manchester M60 1QD, Lancs, England
来源
EUROPHYSICS LETTERS | 2004年 / 68卷 / 01期
关键词
D O I
10.1209/epl/i2004-10166-9
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We consider the dynamics of thermal concentration fluctuations in polymer Langmuir monolayers, probed with surface light scattering. We present data on the proteins beta-lactoglobulin and beta-casein and on the synthetic polymers Poly(vinyl acetate) and Poly(4-hydroxystyrene). We show that for all these systems, in the semi-dilute concentration regime, there is a power law dependency of both the elastic and viscous components of the dilational modulus on the concentration. We find that for all the systems considered, the viscosity scales with a power that is double that of the elasticity. A simple explanation for this universal dynamical behavior in semidilute polymer monolayers is suggested.
引用
收藏
页码:65 / 71
页数:7
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