[(η5-C5H5)(OC3V=B=N(SiMe3)2:: a half-sandwich complex with a terminal borylene ligand

被引：74

作者：

Braunschweig, H

Colling, M

Hu, CH

Radacki, K

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

[2] Rhein Westfal TH Aachen, Inst Anorgan Chem, D-52056 Aachen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 02期

关键词：

boron; borylene complexes; sandwich complexes; vanadium;

D O I：

10.1002/anie.200390079

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A vanadium-boron distance of 1.971 Å characterizes the first classical bond between these two elements. The novel half-sandwich complex 1 was obtained from [(OC)5Cr=B=N(SiMe3)2] by photochemically induced intermetallic borylene transfer.

引用

页码：205 / +

页数：5

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