Ag migration pathways in crystalline and glassy solid electrolytes AgI-AgMxOy

被引：37

作者：

Adams, S ^{[1
]}

Maier, J

机构：

[1] Univ Gottingen, Min Kristallog Inst, Gottingen, Germany

[2] Max Planck Inst Festkorperforsch, Stuttgart, Germany

来源：

SOLID STATE IONICS | 1998年 / 105卷 / 1-4期

关键词：

ion conductivity; conduction pathways; valence sum pseudopotentials; silver ion conductors; glassy electrolytes;

D O I：

10.1016/S0167-2738(97)00450-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Conduction pathways for silver ions in crystalline model structures of the AgI-AgMxOy electrolytes are derived from a bond valence sum model, which proved successful for alpha-AgI. Models for the silver transport in the related glassy phases are discussed in the light of our results.

引用

页码：67 / 74

页数：8

共 12 条

[1] Investigations on silver iodide silver oxysalt glass ceramics
Adams, S
Hariharan, K
Maier, J
[J]. SOLID STATE IONICS, 1996, 86-8 : 503 - 509
[2] INTERFACE EFFECT ON THE SILVER ION CONDUCTIVITY DURING THE CRYSTALLIZATION OF AGI-AG2O-V2O5 GLASSES
ADAMS, S
HARIHARAN, K
MAIER, J
[J]. SOLID STATE IONICS, 1995, 75 : 193 - 201
[3] Crystal structure and Ag+ conductivity of the solid electrolyte Ag8I4V2O7
Adams, S
[J]. ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1996, 211 (11): : 770 - 776
[4] RECENT DEVELOPMENTS IN FAST ION-TRANSPORT IN GLASSY AND AMORPHOUS MATERIALS
ANGELL, CA
[J]. SOLID STATE IONICS, 1986, 18-9 : 72 - 88
[5] CHAN LYY, 1977, J SOLID STATE CHEM, V21, P33
[6] SINGLE-CRYSTAL GROWTH AND STRUCTURE DETERMINATION OF AG16I12P2O7
GARRETT, JD
GREEDAN, JE
FAGGIANI, R
CARBOTTE, S
BROWN, ID
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 1982, 42 (02) : 183 - 190
[7] ANISOTROPIC ELECTRICAL-CONDUCTIVITY AND LOW-TEMPERATURE PHASE-TRANSITIONS OF THE SOLID ELECTROLYTE AG26I18W4O16
GELLER, S
WILBER, SA
RUSE, GF
AKRIDGE, JR
TURKOVIC, A
[J]. PHYSICAL REVIEW B, 1980, 21 (06): : 2506 - 2512
[8] DISTRIBUTION AND ANHARMONIC THERMAL VIBRATION OF CATIONS IN ALPHA-AGI
HOSHINO, S
SAKUMA, T
FUJII, Y
[J]. SOLID STATE COMMUNICATIONS, 1977, 22 (12) : 763 - 765
[9] RECENT PROGRESS IN SUPERIONIC CONDUCTING GLASSES
MINAMI, T
[J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 1987, 95-6 : 107 - 118
[10] RADAEV SF, 1994, Z KRISTALLOGR, V8, P628

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