Phosphomolybdic acid-Al2O3:: A mild, efficient, heterogeneous and reusable catalyst for regioselective opening of oxiranes with amines to β-amino alcohols

被引：35

作者：

Kumar, S. Ramesh ^{[1
]}

Leelavathi, P. ^{[1
]}

机构：

[1] Osmania Univ, Coll Women, Dept Chem, Hyderabad 500095, Andhra Pradesh, India

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2007年 / 266卷 / 1-2期

关键词：

epoxides; amines; solid acid; PMA (phosphomolybdic acid); alumina; 2-amino alcohols;

D O I：

10.1016/j.molcata.2006.10.045

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Epoxides undergo smoothly ring-opening reaction with various amines catalyzed by solid acid containing phosphomolybdic acid-neutral alumina under mild reaction conditions. All the reactions were carried out at room temperature to afford the corresponding beta-amino alcohols in excellent yields and with high regioselectivity. The catalyst was recovered and reused for further reactions with very good efficiency. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：65 / 68

页数：4

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