Direct chiral high performance liquid chromatography separation of O,O-diethyl-(p-methyl-benzenesulfonamido)-aryl (alkyl)-methylphosphonate

被引:17
作者
Gao, RY [1 ]
Yang, GS [1 ]
Shen, HX [1 ]
Chen, RY [1 ]
Dai, Q [1 ]
Wang, QS [1 ]
机构
[1] NANKAI UNIV,DEPT CHEM,TIANJIN 300071,PEOPLES R CHINA
关键词
D O I
10.1080/10826079608005503
中图分类号
Q5 [生物化学];
学科分类号
071010 [生物化学与分子生物学]; 081704 [应用化学];
摘要
The enantiomers of a series of twelve O,O-diethyl, (p-methylbenzenesulfonamido), aryl(alkyl)-methylphosphonates have been separated by high performance liquid chromatography on a Pirkle model chiral stationary phase. Chromatographic data and a chiral recognition model are presented for the separation of these organic phosphorus enantiomers on the chiral phase. The influence of column temperature and flow rate of mobile phase has been described.
引用
收藏
页码:171 / 178
页数:8
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