Selective laser spectroscopy of RE3+ and Mn4+ in sol-gel technique produced Al2O3

被引：25

作者：

Feofilov, SP ^{[1
]}

Kulinkin, AB ^{[1
]}

Kutsenko, AB ^{[1
]}

Zakharchenya, RI ^{[1
]}

机构：

[1] AF Ioffe Phys Tech Inst, St Petersburg 194021, Russia

来源：

JOURNAL OF LUMINESCENCE | 1998年 / 76-7卷

关键词：

nanocrystals; sol-gel technology; rare-earth and transition metal ions;

D O I：

10.1016/S0022-2313(97)00204-4

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

Sol-gel produced nanocrystalline highly porous transparent gamma-Al2O3 doped with RE and TM ions and alpha-Al2O3 ceramics, produced by its annealing, were studied with selective laser spectroscopy techniques. The site-selective spectroscopy of RE3+ ions in alpha-Al2O3 reveals that these ions form centers in corundum with one dominating type. The FLN studies of homogeneous line widths of 5D(0)-F-7(0.1) transition in gamma- and alpha-Al2O3 extend the low-temperature hole-burning data (Feofilov et al., Phys. Rev. B 54 (1996) 3690). It is shown that Mn4+ -doped Al2O3 is potentially effective photochemical hole-burning material and self-gated persistent hole-burning in alpha-Al2O3:Mn was demonstrated. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：217 / 220

页数：4

共 7 条

[1]

Feofilov S. P., 1996, J LUMIN, V66-67, P349

[2] Spectral hole burning in Eu3+-doped highly porous gamma-aluminum oxide [J].

Feofilov, SP ;

Kaplyanskii, AA ;

Zakharchenya, RI ;

Sun, Y ;

Jang, KW ;

Meltzer, RS .

PHYSICAL REVIEW B, 1996, 54 (06) :R3690-R3693

[3] Luminescence and laser spectroscopy of highly porous gamma-Al2O3 doped with 3d- and 4f-ions: Effects of spatial phonon confinement [J].

Feofilov, SP ;

Kaplyanskii, AA ;

Zakharchenya, RI .

JOURNAL OF LUMINESCENCE, 1997, 72-4 :41-42

[4] Sol-gel technology grown monolithic highly porous aluminum oxide with chromium and rare earth ions and size-resonant terahertz acoustic vibrations of nanocrystalline particles [J].

Feofilov, SP ;

Kaplyanskii, AA ;

Kutsenko, AB ;

Vasilevskaya, TN ;

Zakharchenya, RI .

PROCEEDINGS OF THE 13TH INTERNATIONAL CONFERENCE ON DEFECTS IN INSULATING MATERIALS - ICDIM 96, 1997, 239- :687-690

[5]

FEOFILOV SP, 1995, OPT SPECTROSC, V79, P653

[6] SHARP-LINE FLUORESCENCE, ELECTRON PARAMAGNETIC RESONANCE, AND THERMOLUMINESCENCE OF MN4+ IN ALPHA-AL2O3 [J].

GESCHWIND, S ;

KISLIUK, P ;

KLEIN, MP ;

REMEIKA, JP ;

WOOD, DL .

PHYSICAL REVIEW, 1962, 126 (05) :1684-&

[7]

HUBER DL, 1989, MATER SCI FORUM, V50, P77

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