A simple solvothermal route to copper chalcogenides

被引:30
作者
Han, ZH
Li, YP
Zhao, HQ
Yu, SH
Yin, XL
Qian, YT [1 ]
机构
[1] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China
[2] Univ Sci & Technol China, Struct Res Lab, Hefei 230026, Anhui, Peoples R China
基金
中国国家自然科学基金;
关键词
copper chalcogenide; solvothermal; synthesis;
D O I
10.1016/S0167-577X(00)00060-4
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Using copper(I) chloride, sodium oxalate and elemental chalcogen, copper chalcogenide powders were synthesized through a simple solvothermal route. Pseudocubic Cu1.80S and orthorhombic Cu31S16 single phases synthesized in ethylenediamine (En) are made up of polyhedral particles, cubic Cu2-xSe synthesized in pyridine (Py) was irregular in shape, while Cu1.75Te synthesized in distilled water appeared to be spherical. Other chalcogenides were also formed under different conditions. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:366 / 369
页数:4
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