Reaction conducted under rather severe conditions for a colloidal catalyst - Hydroformylation of propylene catalyzed by polymer-protected rhodium colloids

被引：16

作者：

Han, M ^{[1
]}

Liu, HF ^{[1
]}

机构：

[1] CHINESE ACAD SCI,INST CHEM,DIV POLYMER CHEM,BEIJING 100080,PEOPLES R CHINA

来源：

MACROMOLECULAR SYMPOSIA | 1996年 / 105卷

关键词：

D O I：

10.1002/masy.19961050125

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Hydroformylation of propylene has been conducted by a polymer-protected rhodium colloid catalyst with an activity of 130 mol butanal/g atom Rh . h. The near colloid catalyst is stable enough ibr repeated use for 7 times lasting similar to 50 h under the reaction condition (temperature: 363 K, pressure: 40 bar) with a total TON of 5,065 cycle/atom Rh.

引用

页码：179 / 183

页数：5

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