Copper(I) mediated living radical polymerisation in an ionic liquid

被引:365
作者
Carmichael, AJ
Haddleton, DM [1 ]
Bon, SAF
Seddon, KR
机构
[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England
[2] Queens Univ Belfast, QUILL Ctr, Belfast BT9 5AG, Antrim, North Ireland
关键词
D O I
10.1039/b003335i
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
1-Butyl-3-methylimidazolium hexafluorophosphate, a room temperature ionic liquid, has been used as solvent for the copper(I) mediated living radical polymerisation of methyl methacrylate; the rate of reaction is enhanced and narrow polydispersity polymers are obtained which are easily isolated from the catalyst.
引用
收藏
页码:1237 / 1238
页数:2
相关论文
共 16 条
[1]  
ABDULSADA AAK, 1995, Patent No. 21871
[2]   First example of the atom transfer radical polymerisation of an acidic monomer: direct synthesis of methacrylic acid copolymers in aqueous media [J].
Ashford, EJ ;
Naldi, V ;
O'Dell, R ;
Billingham, NC ;
Armes, SP .
CHEMICAL COMMUNICATIONS, 1999, (14) :1285-1286
[3]   COMPLEXATION OF CP2MCL2 IN A CHLOROALUMINATE MOLTEN-SALT - RELEVANCE TO HOMOGENEOUS ZIEGLER-NATTA CATALYSIS [J].
CARLIN, RT ;
WILKES, JS .
JOURNAL OF MOLECULAR CATALYSIS, 1990, 63 (02) :125-129
[4]   Regioselective alkylation in ionic liquids [J].
Earle, MJ ;
McCormac, PB ;
Seddon, KR .
CHEMICAL COMMUNICATIONS, 1998, (20) :2245-2246
[5]   Diels-Alder reactions in ionic liquids - A safe recyclable alternative to lithium perchlorate-diethyl ether mixtures [J].
Earle, MJ ;
McCormac, PB ;
Seddon, KR .
GREEN CHEMISTRY, 1999, 1 (01) :23-25
[6]   Atom transfer radical polymerization of methyl methacrylate initiated by alkyl bromide and 2-pyridinecarbaldehyde imine copper(I) complexes [J].
Haddleton, DM ;
Jasieczek, CB ;
Hannon, MJ ;
Shooter, AJ .
MACROMOLECULES, 1997, 30 (07) :2190-2193
[7]   Atom transfer polymerisation of methyl methacrylate mediated by solid supported copper catalysts [J].
Haddleton, DM ;
Kukulj, D ;
Radigue, AP .
CHEMICAL COMMUNICATIONS, 1999, (01) :99-100
[8]   3-aminopropyl silica supported living radical polymerization of methyl methacrylate: Dichlorotris(triphenylphosphine)ruthenium(II) mediated atom transfer polymerization [J].
Haddleton, DM ;
Duncalf, DJ ;
Kukulj, D ;
Radigue, AP .
MACROMOLECULES, 1999, 32 (15) :4769-4775
[9]   Atom transfer polymerization of methyl methacrylate mediated by alkylpyridylmethanimine type ligands, copper(I) bromide, and alkyl halides in hydrocarbon solution [J].
Haddleton, DM ;
Crossman, MC ;
Dana, BH ;
Duncalf, DJ ;
Heming, AM ;
Kukulj, D ;
Shooter, AJ .
MACROMOLECULES, 1999, 32 (07) :2110-2119
[10]   Copper(I)-mediated living radical polymerization under fluorous biphasic conditions [J].
Haddleton, DM ;
Jackson, SG ;
Bon, SAF .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (07) :1542-1543