Hydrogenation of TiFe by high-energy ball milling

被引：57

作者：

Chiang, CH ^{[1
]}

Chin, ZH ^{[1
]}

Perng, TP ^{[1
]}

机构：

[1] Natl Tsing Hua Univ, Dept Mat Sci & Engn, Hsinchu, Taiwan

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2000年 / 307卷 / 307期

关键词：

hydrogen storage materials; interstitial alloys; transition metal compounds; mechanical alloying;

D O I：

10.1016/S0925-8388(00)00827-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The hydrogenation properties of TiFe, TiFe2 and pure Ti during high-energy ball milling in hydrogen atmosphere were studied. By ball milling, TiFe could absorb hydrogen without activation treatment. For Ti powder, a single phase TiH1.924 was formed. In addition, TiFe2 could also be hydrided by ball milling in hydrogen, which was ascribed to decomposition to form TiFeHx, TiH1.924 and Fe. Based on the hydrogenation properties of Ti, TiFe, and TiFe2 during dynamic ball milling and the thermal stability of the milled powders, it is proposed that the reactions in the milling of TiFe in hydrogen involve four steps: (1) fresh surfaces created by collision with the balls; (2) absorption of hydrogen by the powder; (3) oversaturation of hydrogen in the powder; (4) decomposition of TiFeHx to TiH1.924 and Fe. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：259 / 265

页数：7

共 8 条

[1]

BENJAMIN JS, 1974, METALL T A, V1929, P5

[2] In situ observation of combustion to form TiN during ball milling Ti in nitrogen [J].

Chin, ZH ;

Perng, TP .

APPLIED PHYSICS LETTERS, 1997, 70 (18) :2380-2382

[3] GLASS FORMING ABILITY IN MECHANICALLY ALLOYED FE-ZR [J].

HELLSTERN, E ;

SCHULTZ, L .

APPLIED PHYSICS LETTERS, 1986, 49 (18) :1163-1165

[4] PREPARATION OF AMORPHOUS NI60NB40 BY MECHANICAL ALLOYING [J].

KOCH, CC ;

CAVIN, OB ;

MCKAMEY, CG ;

SCARBROUGH, JO .

APPLIED PHYSICS LETTERS, 1983, 43 (11) :1017-1019

[5] Correlation of substitutional solid solution with hydrogenation properties of TiFe1-xMx (M=Ni, Co, Al) alloys [J].

Lee, SM ;

Perng, TP .

JOURNAL OF ALLOYS AND COMPOUNDS, 1999, 291 (1-2) :254-261

[6] FORMATION OF AN AMORPHOUS ALLOY BY SOLID-STATE REACTION OF THE PURE POLYCRYSTALLINE METALS [J].

SCHWARZ, RB ;

JOHNSON, WL .

PHYSICAL REVIEW LETTERS, 1983, 51 (05) :415-418

[7] FORMATION OF AMORPHOUS-ALLOYS BY THE MECHANICAL ALLOYING OF CRYSTALLINE POWDERS OF PURE METALS AND POWDERS OF INTERMETALLICS [J].

SCHWARZ, RB ;

KOCH, CC .

APPLIED PHYSICS LETTERS, 1986, 49 (03) :146-148

[8] EFFECTS OF RELAXATION ON HYDROGEN ABSORPTION IN FE-TI PRODUCED BY BALL-MILLING [J].

ZALUSKI, L ;

ZALUSKA, A ;

TESSIER, P ;

STROMOLSEN, JO ;

SCHULZ, R .

JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 227 (01) :53-57

← 1 →