The Turnbull correlation and the freezing of stratospheric aerosol droplets

被引:17
作者
MacKenzie, AR
Laaksonen, A
Batris, E
Kulmala, M
机构
[1] Univ Helsinki, Dept Phys, FIN-00014 Helsinki, Finland
[2] Univ Cambridge, Ctr Atmospher Sci, Cambridge CB2 1EW, England
关键词
D O I
10.1029/98JD00169
中图分类号
P4 [大气科学(气象学)];
学科分类号
0706 ; 070601 ;
摘要
An empirical correlation that is important in the calculation of homogeneous freezing probabilities, the "Turnbull correlation" for interfacial tensions, has been reevaluated and applied to systems of interest as possible components of polar stratospheric clouds (PSCs). The systems studied were: sulphuric acid solutions freezing to water ice and sulphuric acid tetrahydrate (SAT); and nitric acid solutions freezing to nitric acid trihydrate (NAT) and nitric acid dihydrate (NAD). The calculations have been compared to experimental data: agreement is generally good, although aerosol freezing experiments, which would rigorously test the theory, have not been made for NAT. Of the three measurements of aerosol freezing to NAD, the calculations are closer to those measurements showing a lower freezing temperature, of about 175-177 K. The comparison substantially improves our confidence in our understanding of the mechanisms of PSC formation. Freezing of stratospheric aerosol to water ice remains the most plausible first step in solid-particle PSC formation if homogeneous freezing is the mechanism by which solid-particle PSC formation occurs.
引用
收藏
页码:10875 / 10884
页数:10
相关论文
共 42 条
[1]   HEAT-CAPACITY CHANGES IN GLASS-FORMING AQUEOUS-SOLUTIONS AND THE GLASS-TRANSITION IN VITREOUS WATER [J].
ANGELL, CA ;
TUCKER, JC .
JOURNAL OF PHYSICAL CHEMISTRY, 1980, 84 (03) :268-272
[2]  
[Anonymous], 1978, Microphysics of Clouds and Precipitation, DOI 10.1007/978-94-009-9905-3
[3]   FTIR STUDIES OF LOW-TEMPERATURE SULFURIC-ACID AEROSOLS [J].
ANTHONY, SE ;
TISDALE, RT ;
DISSELKAMP, RS ;
TOLBERT, MA ;
WILSON, JC .
GEOPHYSICAL RESEARCH LETTERS, 1995, 22 (09) :1105-1108
[4]   INFRARED-SPECTRA OF LARGE ACID HYDRATE CLUSTERS - FORMATION CONDITIONS OF SUBMICRON PARTICLES OF HNO3.2H2O AND HNO3.3H2O [J].
BARTON, N ;
ROWLAND, B ;
DEVLIN, JP .
JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (22) :5848-5851
[5]  
BATRIS E, 1997, THESIS U HELSINKI HE
[6]   Mechanisms and temperatures for the freezing of sulfuric acid aerosols measured by FTIR extinction spectroscopy [J].
Bertram, AK ;
Patterson, DD ;
Sloan, JJ .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (06) :2376-2383
[7]  
BERTRAM AK, 1997, IN PRESS J GEOPHYS R
[8]   Infrared spectroscopy of sulfuric acid water aerosols: Freezing characteristics [J].
Clapp, ML ;
Niedziela, RF ;
Richwine, LJ ;
Dransfield, T ;
Miller, RE ;
Worsnop, DR .
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1997, 102 (D7) :8899-8907
[9]   Crystallization kinetics of nitric acid dihydrate aerosols [J].
Disselkamp, RS ;
Anthony, SE ;
Prenni, AJ ;
Onasch, TB ;
Tolbert, MA .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (21) :9127-9137
[10]   In-situ observations of an Antarctic polar stratospheric cloud: Similarities with Arctic observations [J].
Dye, JE ;
Baumgardner, D ;
Gandrud, BW ;
Drdla, K ;
Barr, K ;
Fahey, DW ;
Delnegro, LA ;
Tabazadeh, A ;
Jonsson, HH ;
Wilson, JC ;
Loewenstein, M ;
Podolske, JR ;
Chan, KR .
GEOPHYSICAL RESEARCH LETTERS, 1996, 23 (15) :1913-1916