Performance of dimethyl ether fuel cells using a Pt-Ru catalyst

被引:13
作者
Haraguchi, T [1 ]
Tsutsumi, Y [1 ]
Takagi, H [1 ]
Tamegai, N [1 ]
Yamashita, S [1 ]
机构
[1] Ibaraki Univ, Ibaraki, Japan
关键词
fuel cell; DME; methanol; polymer; electrolyte; direct; Pt-Ru catalyst;
D O I
10.1002/eej.20072
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Phenomena are presented whereby the performance of a dimethyl ether fuel cell (DDFC) at 80 degreesC is much lower when a Pt-Ru catalyst is used on the anode than when a Pt catalyst is used, in contrast to the higher performance achieved using a Pt-Ru catalyst over a Pt catalyst in direct methanol fuel cells (DMFC). The DDFC performance achieved using a Pt-RU catalyst increases with temperature and exceeds that using a Pt catalyst at temperatures over 100 degreesC. After high-temperature operation, the performance of DDFC using a Pt-RU catalyst at 80 degreesC is improved. By supplying sufficient steam before operation, the performance of DDFC using a Pt-RU catalyst at 80 degreesC is also found to improve. Before and during operation, more steam is needed for stable operation of the DDFC using a Pt-RU catalyst at 80 degreesC than using a Pt catalyst. (C) 2004 Wiley Periodicals, Inc.
引用
收藏
页码:19 / 25
页数:7
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