Measurement and modelling of carbon monoxide poisoning distribution within a polymer electrolyte fuel cell

被引：43

作者：

Brett, D. J. L. ^{[1
]}

Aguiar, P.

Brandon, N. P.

Kucernak, A. R.

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem Engn, London SW7 2AZ, England

[2] Univ London Imperial Coll Sci Technol & Med, Dept Earth Sci & Engn, London SW7 2AZ, England

[3] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2007年 / 32卷 / 07期

基金：

英国工程与自然科学研究理事会;

关键词：

polymer electrolyte fuel cell; catalyst poisoning; carbon monoxide;

D O I：

10.1016/j.ijhydene.2007.01.019

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The distribution of carbon monoxide (CO) across the anode of a polymer electrolyte fuel cell with a single channel flow-field is modelled and compared with experimental results obtained using localised stripping voltammetry. Good agreement is observed between experiment and model over a wide range of CO carrier gas flow rates. The model is used to predict the effect of CO transient poisoning, expected to occur during system start-up, when high CO slippage is likely to occur from the fuel processor and the fuel cell is not electrically loaded. (c) 2007 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.

引用

页码：863 / 871

页数：9

共 22 条

[1] Carbon monoxide poisoning of proton exchange membrane fuel cells [J].

Baschuk, JJ ;

Li, XG .

INTERNATIONAL JOURNAL OF ENERGY RESEARCH, 2001, 25 (08) :695-713

[2] Modelling CO poisoning and O2 bleeding in a PEM fuel cell anode [J].

Baschuk, JJ ;

Li, XG .

INTERNATIONAL JOURNAL OF ENERGY RESEARCH, 2003, 27 (12) :1095-1116

[3] The potential of model studies for the understanding of catalyst poisoning and temperature effects in polymer electrolyte fuel cell reactions [J].

Behm, RJ ;

Jusys, Z .

JOURNAL OF POWER SOURCES, 2006, 154 (02) :327-342

[4] Investigation of reactant transport within a polymer electrolyte fuel cell using localised CO stripping voltammetry and adsorption transients [J].

Brett, DJL ;

Atkins, S ;

Brandon, NP ;

Vesovic, V ;

Vasileiadis, N ;

Kucernak, AR .

JOURNAL OF POWER SOURCES, 2004, 133 (02) :205-213

[5] Localized impedance measurements along a single channel of a solid polymer fuel cell [J].

Brett, DJL ;

Atkins, S ;

Brandon, NP ;

Vesovic, V ;

Vasileiadis, N ;

Kucernak, A .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2003, 6 (04) :A63-A66

[6] Measurement of the current distribution along a single flow channel of a solid polymer fuel cell [J].

Brett, DJL ;

Atkins, S ;

Brandon, NP ;

Vesovic, V ;

Vasileiadis, N ;

Kucernak, AR .

ELECTROCHEMISTRY COMMUNICATIONS, 2001, 3 (11) :628-632

[7]

CUSSLER EL, 1997, DIFFUSION MASS TRANS, P102

[8] NATURE OF CO ADSORPTION DURING H-2 OXIDATION IN RELATION TO MODELING FOR CO POISONING OF A FUEL-CELL ANODE [J].

DHAR, HP ;

CHRISTNER, LG ;

KUSH, AK .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (12) :3021-3026

[9]

ESSALIK A, 1995, J APPL ELECTROCHEM, V25, P404

[10]

*FEMLAB, 2001, FEMLAB 3 0 US GUID

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