Scaling out the density dependence of the a relaxation in glass-forming polymers

被引:206
作者
Alba-Simionesco, C
Cailliaux, A
Alegría, A
Tarjus, G
机构
[1] Univ Paris 11, Chim Phys Lab, F-91405 Orsay, France
[2] Univ Basque Country, Dept Fis Mat, E-20080 San Sebastian, Spain
[3] Univ Basque Country, CSIC, Unidad Fis Mat, E-20080 San Sebastian, Spain
[4] Univ Paris 06, Phys Theor Liquides Lab, F-75252 Paris 05, France
来源
EUROPHYSICS LETTERS | 2004年 / 68卷 / 01期
关键词
D O I
10.1209/epl/i2004-10214-6
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We show that the density and temperature dependences of the alpha-relaxation time of several glass-forming polymers can be described through a single scaling variable X = e(rho)/T where e(rho) is well fitted by a power law rho(x), x being a species-specific parameter. This implies that "fragility" is an intrinsic, density-independent property of a glass-former characterizing its super-Arrhenius slowing-down of relaxations, and it leads us to propose a modification of the celebrated Angell plot.
引用
收藏
页码:58 / 64
页数:7
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