Highly Permeable Zeolite Imidazolate Framework-8 Membranes for CO2/CH4 Separation

被引：863

作者：

Venna, Surendar R. ^{[1
]}

Carreon, Moises A. ^{[1
]}

机构：

[1] Univ Louisville, Dept Chem Engn, Louisville, KY 40292 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 01期

关键词：

METAL-ORGANIC FRAMEWORK; SAPO-34; MEMBRANES; CARBON-DIOXIDE; GAS SEPARATION; PERFORMANCE; MIXTURES; CRYSTALS; GROWTH; CO2;

D O I：

10.1021/ja909263x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

ZIF-8 membranes, a type of zeolite imidazolate framework, were synthesized by secondary seeded growth on tubular alpha-Al2O3 porous supports. The presence of small, highly crystalline, microporous crystals with narrow particle size distribution led to continuous thin membranes. The synthesized novel ZIF-8 membranes displayed unprecedented high CO2 permeances and relatively high separation indexes for equimolar mixtures of CO2 and CH4.

引用

页码：76 / +

页数：5

共 42 条

[1] High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture [J].

Banerjee, Rahul ;

Phan, Anh ;

Wang, Bo ;

Knobler, Carolyn ;

Furukawa, Hiroyasu ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

SCIENCE, 2008, 319 (5865) :939-943

[2] Control of Pore Size and Functionality in Isoreticular Zeolitic Imidazolate Frameworks and their Carbon Dioxide Selective Capture Properties [J].

Banerjee, Rahul ;

Furukawa, Hiroyasu ;

Britt, David ;

Knobler, Carolyn ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (11) :3875-+

[3] Solvent resistant nanofiltration (SRNF) membranes based on metal-organic frameworks [J].

Basu, Subhankar ;

Maes, Michael ;

Cano-Odena, Angels ;

Alaerts, Luc ;

De Vos, Dirk E. ;

Vankelecom, Ivo F. J. .

JOURNAL OF MEMBRANE SCIENCE, 2009, 344 (1-2) :190-198

[4] Alumina-supported SAPO-34 membranes for CO2/CH4 separation [J].

Carreon, Moises A. ;

Li, Shiguang ;

Falconer, John L. ;

Noble, Richard D. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (16) :5412-+

[5] SAPO-34 seeds and membranes prepared using multiple structure directing agents [J].

Carreon, Moises A. ;

Li, Shiguang ;

Falconer, John L. ;

Noble, Richard D. .

ADVANCED MATERIALS, 2008, 20 (04) :729-+

[6] Rapid Room-Temperature Synthesis and Characterization of Nanocrystals of a Prototypical Zeolitic Imidazolate Framework [J].

Cravillon, Janosch ;

Muenzer, Simon ;

Lohmeier, Sven-Jare ;

Feldhoff, Armin ;

Huber, Klaus ;

Wiebcke, Michael .

CHEMISTRY OF MATERIALS, 2009, 21 (08) :1410-1412

[7] Preparation and gas separation performance of zeolite T membrane [J].

Cui, Y ;

Kita, H ;

Okamoto, K .

JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (05) :924-932

[8] ZEOLITE SYNTHESIS USING A SEMICONTINUOUS REACTOR .1. CONTROLLED NUCLEATION AND GROWTH OF ZSM-5 CRYSTALS HAVING WELL-DEFINED MORPHOLOGIES [J].

CUNDY, CS ;

HENTY, MS ;

PLAISTED, RJ .

ZEOLITES, 1995, 15 (04) :353-372

[9]

*DEP EN, 2008, 0383 DOEEIA

[10] Manufacture of dense coatings of Cu3(BTC)2 (HKUST-1) on α-alumina [J].

Gascon, Jorge ;

Aguado, Sonia ;

Kapteijn, Freek .

MICROPOROUS AND MESOPOROUS MATERIALS, 2008, 113 (1-3) :132-138

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