Addition and coupling reactions of bis(pinacolato)diboron mediated by CuCl in the presence of potassium acetate

被引：237

作者：

Takahashi, K ^{[1
]}

Ishiyama, T ^{[1
]}

Miyaura, N ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Engn, Div Mol Chem, Sapporo, Hokkaido 0608628, Japan

来源：

CHEMISTRY LETTERS | 2000年 / 09期

关键词：

D O I：

10.1246/cl.2000.982

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The addition of bis(pinacolato)diboron [(Me4C2O2)B-B(O2C2Me4)] to alpha,beta-unsaturated ketones, esters, nitriles, or terminal alkynes and the coupling with allyl chlorides were carried out in DMF at room temperature in the presence of CuCl and AcOK. The transmetalation from boron to copper generating a B-Cu species was proposed as the key step of the reactions.

引用

页码：982 / 983

页数：2

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