Low-temperature chemical synthesis of nanocrystalline MgAl2O4 spinel powder

被引：64

作者：

Pati, RK ^{[1
]}

Pramanik, P ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Kharagpur 721302, W Bengal, India

来源：

JOURNAL OF THE AMERICAN CERAMIC SOCIETY | 2000年 / 83卷 / 07期

关键词：

D O I：

10.1111/j.1151-2916.2000.tb01473.x

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Nanocrystalline MgAl2O4 spinel powder was synthesized by pyrolysis of complex compounds of aluminum and magnesium with triethanolamine (TEA). The soluble metal ion-TEA complexes formed the precursor material on complete dehydration of the complexes of aluminum-TEA and magnesium-TEA. Single-phase MgAl2O4 spinel powder resulted after heat treatment of the precursor material at 675 degrees C. The precursor and the heat-treated powders mere characterized by X-ray diffractometry (XRD), differential thermal and thermogravimetric analysis, and transmission electron microscopy (TEM). The average crystallite size as measured from the X-ray line broadening was around 14 nm and the average particle size from TEM studies was around 20 nm.

引用

页码：1822 / 1824

页数：3

共 12 条

[1] Characterization of ZnAl2O4 nanocrystals prepared by the polyvinyl alcohol evaporation route [J].

Adak, AK ;

Pathak, A ;

Pramanik, P .

JOURNAL OF MATERIALS SCIENCE LETTERS, 1998, 17 (07) :559-561

[2]

[Anonymous], 1992, MAT LETT

[3] SUBMICRONIC MGAL2O4 POWDER SYNTHESIS IN SUPERCRITICAL ETHANOL [J].

BARJ, M ;

BOCQUET, JF ;

CHHOR, K ;

POMMIER, C .

JOURNAL OF MATERIALS SCIENCE, 1992, 27 (08) :2187-2192

[4]

BRATTON RJ, 1969, AM CERAM SOC BULL, V48, P759

[5] Low-temperature preparation of nanocrystalline lead zirconate titanate and lead lanthanum zirconate titanate powders using triethanolamine [J].

Das, RN ;

Pathak, A ;

Pramanik, P .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1998, 81 (12) :3357-3360

[6]

Klug M.P., 1974, X-Ray Diffraction Procedures: Fo Polycrystalline and Amorphous Materials, Vsecond, P634

[7] REACTIONS IN SUPERCRITICAL FLUIDS, A NEW ROUTE FOR OXIDE CERAMIC POWDER ELABORATION - SYNTHESIS OF THE SPINEL MGAL2O4 [J].

POMMIER, C ;

CHHOR, K ;

BOCQUET, JF ;

BARJ, M .

MATERIALS RESEARCH BULLETIN, 1990, 25 (02) :213-221

[8] Synthesis of nanoparticle of inorganic oxides by polymer matrix [J].

Pramanik, P .

BULLETIN OF MATERIALS SCIENCE, 1995, 18 (06) :819-829

[9] Chemical synthesis of nanosized oxides [J].

Pramanik, P .

BULLETIN OF MATERIALS SCIENCE, 1996, 19 (06) :957-961

[10]

Ryskhewitch E., 1960, OXIDE CERAMICS, P271

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