Gold-Catalyzed Ethynylation of Arenes

被引：294

作者：

de Haro, Teresa ^{[1
]}

Nevado, Cristina ^{[1
]}

机构：

[1] Univ Zurich, Inst Organ Chem, CH-8057 Zurich, Switzerland

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 05期

关键词：

CROSS-COUPLING REACTIONS; C-H BONDS; NONACTIVATED ARENES; HYDROGEN; HYDROARYLATION; ACTIVATION; COMPLEXES; GOLD(III); ALKYNES;

D O I：

10.1021/ja909726h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel gold-catalyzed ethynylation of aromatic rings with electron-deficient alkynes via gold catalyzed C-H activation of both C-sp-H and C-sp(2)-H bonds has been developed. This transformation provides aromatic propiolates difficult to prepare by other methods, highlighting the synthetic potential of gold chemistry.

引用

页码：1512 / +

页数：4

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