Hydrothermal synthesis and crystal structures of two bimetallic chain-like and cluster complexes [{Co(phen)2}2V6O17]n and [{Cu(phen)2}4V10O29]•6H2O

被引：132

作者：

Zhang, XM

Tong, ML

Chen, XM ^{[1
]}

机构：

[1] Zhongshan Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China

[2] Zhongshan Univ, State Key Lab Ultrafast Laser Spect, Guangzhou 510275, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 18期

关键词：

D O I：

10.1039/b005880g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two complexes, [{Co(phen)(2)}(2)V6O17](n) 1 and [{Cu(phen)(2)}(4)- V10O29]. 6H(2)O 2, have been hydrothermally synthesized; X-ray crystallography shows that 1 consists of one-dimensional stepped chains built up from covalently linked {V6O17}(n)(4n-) chains and [Co(phen)(2)](2+) fragments while 2 is composed of a discrete V10O298- cluster covalently attached to four [Cu(phen)(2)](2+) fragments.

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页码：1817 / 1818

页数：2

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