Direct observation of the geometry of atom-atom and atom-molecule collisions

被引：19

作者：

Grosser, J ^{[1
]}

Hoffmann, O ^{[1
]}

Rakete, C ^{[1
]}

Rebentrost, F ^{[1
]}

机构：

[1] MAX PLANCK INST QUANTUM OPT, D-85748 GARCHING, GERMANY

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 1997年 / 101卷 / 41期

关键词：

D O I：

10.1021/jp970904f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report crossed beam experiments on the laser assisted collisions Na(3s) + M + h upsilon --> Na(3p) + M with M = Kr, N-2, and CO2. By varying the photon polarization, we gain direct insight into the geometric properties of the collision complex. For the Na + Kr system, we are able to deduce from the experimental data the two possible directions (Condon vectors) of the internuclear axis at the moment of the optical transition.

引用

页码：7627 / 7633

页数：7

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