Synthesis of novel acetylenic cyclophanes with helical chirality: Potential new structures for liquid crystals

被引:48
作者
Collins, SK [1 ]
Yap, GPA [1 ]
Fallis, AG [1 ]
机构
[1] Univ Ottawa, Dept Chem, Ottawa, ON K1N 6N5, Canada
关键词
D O I
10.1021/ol000199k
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] The synthesis of a series of novel acetylenic cyclophanes is described. X-ray crystallographic analysis of the core structure revealed a twisted conformation with helical chirality. Preliminary results suggest that these cyclophanes, with appropriate functionality, have the potential to act as unique liquid crystalline materials.
引用
收藏
页码:3189 / 3192
页数:4
相关论文
共 35 条
  • [1] [Anonymous], 1994, TOP CURR CHEM, P172
  • [2] [Anonymous], 1983, TOP CURR CHEM, P113
  • [3] FERROELECTRIC BEHAVIOR IN METAL-CONTAINING LIQUID-CRYSTALS - A STRUCTURE-ACTIVITY STUDY
    BAENA, MJ
    BARBERA, J
    ESPINET, P
    EZCURRA, A
    ROS, MB
    SERRANO, JL
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (05) : 1899 - 1906
  • [4] The new inductees in the ''Hall of Phane'' - No Phane, no gain
    Bodwell, GJ
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (18): : 2085 - 2088
  • [5] Synthesis, crystal structure, and explosive decomposition of 1,2:5,6:11,12:15,16-tetrabenzo-3,7,9,13,17,19-hexadehydro[20]annulene: Formation of onion- and tube-like closed-shell carbon particles
    Boese, R
    Matzger, AJ
    Vollhardt, KPC
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (08) : 2052 - 2053
  • [6] Collins SK, 2000, ANGEW CHEM INT EDIT, V39, P385, DOI 10.1002/(SICI)1521-3773(20000117)39:2<385::AID-ANIE385>3.0.CO
  • [7] 2-I
  • [8] deMeijere A, 1997, SYNLETT, P1221
  • [9] Diederich F., 1991, CYCLOPHANES
  • [10] Synthesis of conjugated helical acetylene-bridged polymers and cyclophanes
    Fox, JM
    Lin, D
    Itagaki, Y
    Fujita, T
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (06) : 2031 - 2038