Development and application of a simple capillary-microreactor for oxidation of glucose with a porous gold catalyst

被引：34

作者：

Basheer, C

Swaminathan, S

Lee, HK

Valiyaveettil, S

机构：

[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

[2] Natl Univ Singapore, NUS Nanosci & Nanotechnol Initiat, Singapore 117542, Singapore

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 03期

关键词：

D O I：

10.1039/b414429e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient oxidation of glucose to gluconic acid was performed using a porous gold( 0) catalyst in a low-cost microreactor designed from Pyrex glass capillary tubing; compared with the conventional synthesis procedure this novel approach of using a capillary-microreactor offers a convenient and highly efficient means to optimise reaction conditions and catalytic activities.

引用

收藏

页码：409 / 410

页数：2

相关论文

共 20 条

[1] ELECTROCHEMICAL OXIDATION OF GLUCOSE ON SINGLE-CRYSTAL GOLD SURFACES [J].

ADZIC, RR ;

HSIAO, MW ;

YEAGER, EB .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1989, 260 (02) :475-485

[2]

Aoun S. B., 2004, J ELECTROANAL CHEM, V567, P175, DOI DOI 10.1016/J.JELECHEM.2003.12.022

[3] Selective oxidation of D-glucose on gold catalyst [J].

Biella, S ;

Prati, L ;

Rossi, M .

JOURNAL OF CATALYSIS, 2002, 206 (02) :242-247

[4] Gold: a relatively new catalyst [J].

Bond, GC .

CATALYSIS TODAY, 2002, 72 (1-2) :5-9

[5]

BOND GC, 1999, CATAL REV SCI ENG, V41, P391

[6]

Ehrfeld W., 2000, Microreactors: new technology for modern chemistry, DOI DOI 10.1002/3527601953

[7] Chemical and biochemical microreactors [J].

Haswell, S ;

Skelton, V .

TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 2000, 19 (06) :389-395

[8] Preparation of large-area 3D ordered macroporous titania films by silica colloidal crystal templating [J].

Kuai, S ;

Badilescu, S ;

Bader, G ;

Brüning, R ;

Hu, XF ;

Truong, VV .

ADVANCED MATERIALS, 2003, 15 (01) :73-+

[9] Special feature section: Process intensification/continuous processing in the fine chemicals arena [J].

Laird, T .

ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2001, 5 (06) :612-612

[10] OXIDATION OF ALCOHOLS WITH MOLECULAR-OXYGEN ON PLATINUM METAL-CATALYSTS IN AQUEOUS-SOLUTIONS [J].

MALLAT, T ;

BAIKER, A .

CATALYSIS TODAY, 1994, 19 (02) :247-283