Study of nitrogen adsorbed on open-ended nanotube bundles

被引:41
作者
Yoo, DH
Rue, GH
Chan, MHW
Hwang, YH
Kim, HK [1 ]
机构
[1] Pusan Natl Univ, Dept Phys, Pusan 609735, South Korea
[2] Pusan Natl Univ, RCDAMP, Pusan 609735, South Korea
[3] Kyungpook Natl Univ, Sch Elect & Elect Engn, Taegu 702701, South Korea
[4] Penn State Univ, Dept Phys, University Pk, PA 16802 USA
关键词
D O I
10.1021/jp026925d
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The adsorption of N-2 on the open-ended single-walled carbon nanotube bundles was studied. The amount corresponding to the first coverage adsorbed on open-ended carbon nanotube bundles is three times larger than the amount adsorbed on closed-ended nanotube bundles. The isosteric heat of adsorption was obtained from the adsorption isotherm measurement performed at temperatures ranging from 117 to 130 K. The estimated heat of adsorption of nitrogen on the open-ended nanotube bundles is about twice as great as that on the closed-ended nanotube bundles. This leads directly to the conclusion that the binding energy of nitrogen on the open-ended nanotube is greater than that of nitrogen on the closed-ended nanotube bundles.
引用
收藏
页码:1540 / 1542
页数:3
相关论文
共 19 条
[1]   Theoretical study of lithium-doped polycyclic aromatic hydrocarbons [J].
Ago, H ;
Nagata, K ;
Yoshizawa, K ;
Tanaka, K ;
Yamabe, T .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1997, 70 (07) :1717-1726
[2]   THERMODYNAMIC STUDY OF PHASE-TRANSITIONS OF MONOLAYER N-2 ON GRAPHITE [J].
CHAN, MHW ;
MIGONE, AD ;
MINER, KD ;
LI, ZR .
PHYSICAL REVIEW B, 1984, 30 (05) :2681-2694
[3]   Nanotubes as nanoprobes in scanning probe microscopy [J].
Dai, HJ ;
Hafner, JH ;
Rinzler, AG ;
Colbert, DT ;
Smalley, RE .
NATURE, 1996, 384 (6605) :147-150
[4]  
Dash J.G., 1975, FILMS SOLID SURFACES
[5]   Electron field emitters based on carbon nanotube films [J].
deHeer, WA ;
Bonard, JM ;
Fauth, K ;
Chatelain, A ;
Forro, L ;
Ugarte, D .
ADVANCED MATERIALS, 1997, 9 (01) :87-&
[6]   Storage of hydrogen in single-walled carbon nanotubes [J].
Dillon, AC ;
Jones, KM ;
Bekkedahl, TA ;
Kiang, CH ;
Bethune, DS ;
Heben, MJ .
NATURE, 1997, 386 (6623) :377-379
[7]   CAPILLARITY AND WETTING OF CARBON NANOTUBES [J].
DUJARDIN, E ;
EBBESEN, TW ;
HIURA, H ;
TANIGAKI, K .
SCIENCE, 1994, 265 (5180) :1850-1852
[8]   Physical adsorption of xenon in open single walled carbon nanotubes: Observation of a quasi-one-dimensional confined Xe phase [J].
Kuznetsova, A ;
Yates, JT ;
Liu, J ;
Smalley, RE .
JOURNAL OF CHEMICAL PHYSICS, 2000, 112 (21) :9590-9598
[9]   Fullerene pipes [J].
Liu, J ;
Rinzler, AG ;
Dai, HJ ;
Hafner, JH ;
Bradley, RK ;
Boul, PJ ;
Lu, A ;
Iverson, T ;
Shelimov, K ;
Huffman, CB ;
Rodriguez-Macias, F ;
Shon, YS ;
Lee, TR ;
Colbert, DT ;
Smalley, RE .
SCIENCE, 1998, 280 (5367) :1253-1256
[10]   A molecular simulation study of freezing/melting phenomena for Lennard-Jones methane in cylindrical nanoscale pores [J].
Maddox, MW ;
Gubbins, KE .
JOURNAL OF CHEMICAL PHYSICS, 1997, 107 (22) :9659-9667