Inelastic electron tunneling spectroscopy on decanethiol at elevated temoeratures

被引：34

作者：

Hallbäck, AS

Oncel, N

Huskens, J

Zandvliet, HJW

Poelsema, B

机构：

[1] Univ Twente, Solid State Phys Grp, NL-7500 AE Enschede, Netherlands

[2] Univ Twente, MESA, Inst Nanotechnol, NL-7500 AE Enschede, Netherlands

[3] Univ Twente, Supramol Chem & Technol Grp, NL-7500 AE Enschede, Netherlands

来源：

NANO LETTERS | 2004年 / 4卷 / 12期

关键词：

D O I：

10.1021/nl0485253

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Inelastic electron tunneling spectroscopy (IETS) measurements using scanning tunneling microscopy (STM) on a decanethiol self-assembled monolayer on Au(111) are presented. The results presented are obtained in the temperature range 77-300 K, which is a much higher temperature than what is commonly used for STM-IETS measurements. Two peaks at +/-34 meV (probably Au-S or S-C stretch mode) and +/-156 meV (C-C stretch mode or a CH2 mode) are resolved.

引用

收藏

页码：2393 / 2395

页数：3

相关论文

共 11 条

[1] Single-molecule chemistry [J].

Ho, W .

JOURNAL OF CHEMICAL PHYSICS, 2002, 117 (24) :11033-11061

[2] MOLECULAR VIBRATION SPECTRA BY ELECTRON TUNNELING [J].

JAKLEVIC, RC ;

LAMBE, J .

PHYSICAL REVIEW LETTERS, 1966, 17 (22) :1139-&

[3] An HREELS study of alkanethiol self-assembled monolayers on Au(111) [J].

Kato, HS ;

Noh, J ;

Hara, M ;

Kawai, M .

JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (37) :9655-9658

[4] THEORY OF VIBRATIONAL MODE INTENSITIES IN INELASTIC ELECTRON-TUNNELING SPECTROSCOPY [J].

KIRTLEY, J ;

SCALAPINO, DJ ;

HANSMA, PK .

PHYSICAL REVIEW B, 1976, 14 (08) :3177-3184

[5] Characterization of organosulfur molecular monolayers on Au(111) using scanning tunneling microscopy [J].

Poirier, GE .

CHEMICAL REVIEWS, 1997, 97 (04) :1117-1127

[6] THE C(4X2) SUPERLATTICE OF N-ALKANETHIOL MONOLAYERS SELF-ASSEMBLED AN AU(111) [J].

POIRIER, GE ;

TARLOV, MJ .

LANGMUIR, 1994, 10 (09) :2853-2856

[7] Inelastic tunneling spectroscopy using scanning tunneling microscopy on trans-2-butene molecule: Spectroscopy and mapping of vibrational feature [J].

Sainoo, Y ;

Kim, Y ;

Komeda, T ;

Kawai, M .

JOURNAL OF CHEMICAL PHYSICS, 2004, 120 (16) :7249-7251

[8] WHAT ARE THE HOLES IN SELF-ASSEMBLED MONOLAYERS OF ALKANETHIOLS ON GOLD [J].

SCHONENBERGER, C ;

SONDAGHUETHORST, JAM ;

JORRITSMA, J ;

FOKKINK, LGJ .

LANGMUIR, 1994, 10 (03) :611-614

[9] Single-molecule vibrational spectroscopy and microscopy [J].

Stipe, BC ;

Rezaei, MA ;

Ho, W .

SCIENCE, 1998, 280 (5370) :1732-1735

[10] Inelastic electron tunneling spectroscopy of an alkanedithiol self-assembled monolayer [J].

Wang, WY ;

Lee, T ;

Kretzschmar, I ;

Reed, MA .

NANO LETTERS, 2004, 4 (04) :643-646