Inorganic particle toughening I: micro-mechanical deformations in the fracture of glass bead filled epoxies

被引:116
作者
Lee, J [1 ]
Yee, AF [1 ]
机构
[1] Univ Michigan, Macromol Sci & Engn Program, Ann Arbor, MI 48109 USA
基金
美国国家卫生研究院;
关键词
epoxy; fracture; toughening;
D O I
10.1016/S0032-3861(00)00397-9
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
General characteristics of micro-mechanical deformations found in the fracture of various glass bead filled epoxies are investigated. Among the various types of step features on fracture surfaces, the basic longitudinal texture is not influenced by the existence of glass beads, but most other steps formed are significantly affected. Various microscopic investigations show that microcracking does not extensively occur in the fracture of glass bead filled epoxies. Microcracking other than debonding of glass beads is seldom observed, and furthermore, debonding is found to occur only on and near the fracture surface. Micro-shear bands are clearly identified and distinguished from microcracks found in unnotched tensile specimens. Based on examination of micro-mechanical deformations, three types of fracture processes are proposed for glass bead filled epoxies having different glass bead contents and interfacial strengths. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:577 / 588
页数:12
相关论文
共 65 条
[1]   PLASTIC DEFORMATION BANDS IN GLASSY POLYSTYRENE [J].
ARGON, AS ;
ANDREWS, RD ;
GODRICK, JA ;
WHITNEY, W .
JOURNAL OF APPLIED PHYSICS, 1968, 39 (03) :1899-&
[2]  
ATKINSON C, 1982, INT J FRACTURE, V18, P279
[3]   FRACTOGRAPHY OF HIGHLY CROSSLINKED POLYMERS [J].
ATSUTA, M ;
TURNER, DT .
JOURNAL OF MATERIALS SCIENCE LETTERS, 1982, 1 (04) :167-169
[4]   Fatigue of hybrid epoxy composites: Epoxies containing rubber and hollow glass spheres [J].
Azimi, HR ;
Pearson, RA ;
Hertzberg, RW .
POLYMER ENGINEERING AND SCIENCE, 1996, 36 (18) :2352-2365
[5]   MECHANISMS OF FRACTURE IN FILLED THERMOSETTING RESINS [J].
BROWN, SK .
BRITISH POLYMER JOURNAL, 1980, 12 (01) :24-30
[6]   CAVITATION IN MODEL ELASTOMERIC COMPOSITES [J].
CHO, K ;
GENT, AN .
JOURNAL OF MATERIALS SCIENCE, 1988, 23 (01) :141-144
[7]  
Clyne T.W., 1993, INTRO METAL MATRIX C
[8]   BASIC LONGITUDINAL TEXTURE AND FRACTURING PROCESS IN THERMOSET POLYMERS [J].
COVAVISARUCH, JS ;
ROBERTSON, RE ;
FILISKO, FE .
JOURNAL OF MATERIALS SCIENCE, 1992, 27 (04) :990-1000
[9]   HEALING OF CRACKS IN CARBON-FIBER PEEK COMPOSITES [J].
DAVIES, P ;
CANTWELL, W ;
KAUSCH, HH .
JOURNAL OF MATERIALS SCIENCE LETTERS, 1989, 8 (11) :1247-1248
[10]   THE MECHANISM FOR CRAZE-TIP ADVANCE IN GLASSY-POLYMERS [J].
DONALD, AM ;
KRAMER, EJ .
PHILOSOPHICAL MAGAZINE A-PHYSICS OF CONDENSED MATTER STRUCTURE DEFECTS AND MECHANICAL PROPERTIES, 1981, 43 (04) :857-870