Selective air oxidation of dimethyl sulfide to dimethyl sulfoxide catalysed by aminopolycarboxylatoruthenium(III) complex

被引：23

作者：

Chatterjee, D ^{[1
]}

机构：

[1] Cent Salt & Marine Chem Res Inst, Discipline Coordinat Chem, Bhavnagar 364002, Gujarat, India

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1997年 / 127卷 / 1-3期

关键词：

oxidation; dimethylsulfide; dimethylsulfoxide; aminocarboxylate; catalysis;

D O I：

10.1016/S1381-1169(97)00125-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Reactions of (RuL)-L-III(H2O) (L = aminopolycarboxylic ligands viz. edta, pdta, hedtra) with dimethylsulfide (DMS) and dimethylsulfoxide (DMSO) were studied by using spectrophotometric, electrochemical and kinetic methods. [Ru-III(DMS)] complexes formed by the interaction of (RuL)-L-III(H2O) and DMS undergo oxidation when exposed to air to yield DMSO and (RuL)-L-III(H2O) back. Under identical condition [(RuL)-L-III(DMSO)] complexes do not undergo any further oxidation to produce dimethyl sulfone. (C) 1997 Elsevier Science B.V.

引用

页码：57 / 60

页数：4

共 16 条

[1]

CHATTERJEE D, 1993, INDIAN J CHEM A, V32, P772

[2]

DIAMANTIS AA, 1981, INORG CHEM, V20, P1992

[3] OXIDATIONS WITH RUTHENIUM TETROXIDE [J].

DJERASSI, C ;

ENGLE, RR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1953, 75 (15) :3838-3840

[4]

EDWARDS JD, 1962, PEROXIDE REACTION ME, P96

[5] SYNTHESIS OF THE MONOOXORUTHENIUM(V) COMPLEXES CONTAINING THE AMINO POLYCARBOXYLIC ACID LIGANDS EDTA AND PDTA AND THEIR REACTIVITIES IN THE OXIDATION OF ORGANIC SUBSTRATES - X-RAY CRYSTAL-STRUCTURES OF K[RUIII(EDTA-H)CL].2H2O AND K[RUIII(PDTA-H)CL].0.5H2O [J].

KHAN, MMT ;

CHATTERJEE, D ;

MERCHANT, RR ;

PAUL, P ;

ABDI, SHR ;

SRINIVAS, D ;

SIDDIQUI, MRH ;

MOIZ, MA ;

BHADBHADE, MM ;

VENKATASUBRAMANIAN, K .

INORGANIC CHEMISTRY, 1992, 31 (13) :2711-2718

[6] KINETICS AND MECHANISM OF OXIDATION OF DIMETHYL SULFIDE WITH MOLECULAR-OXYGEN CATALYZED BY K[RUIII(EDTA-H)CL] COMPLEX IN WATER DIOXAN MEDIUM [J].

KHAN, MMT ;

BAJAJ, HC ;

CHATTERJEE, D .

JOURNAL OF MOLECULAR CATALYSIS, 1992, 71 (02) :177-182

[7] A RUTHENIUM(III) ANALOG OF THE UDENFRIEND SYSTEM - RU(III)-EDTA-ASCORBATE-MOLECULAR OXYGEN IN THE EFFECTIVE OXYGEN ATOM TRANSFER-REACTION OF SATURATED AND UNSATURATED ORGANIC-COMPOUNDS [J].

KHAN, MMT ;

SHUKLA, RS ;

RAO, AP .

INORGANIC CHEMISTRY, 1989, 28 (03) :452-458

[8]

KHAN MMT, 1986, J CHEM RES S, P1001

[9] CATALYTIC SYNTHESIS OF SULFOXIDES AND SULFONES VIA OXIDATION OF SULFIDES BY MOLECULAR-OXYGEN [J].

MASHKINA, AV .

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 1990, 32 (1-2) :105-161

[10]

Oae S., 1977, ORGANIC CHEM SULFUR

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