Co-chelation of a scorpion-shaped carboxylate ligand and phenanthroline lead to a 2-D interpenetratively tubular architecture

被引:47
作者
Cao, XY [1 ]
Zhang, J [1 ]
Cheng, JK [1 ]
Kang, Y [1 ]
Yao, YG [1 ]
机构
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China
来源
CRYSTENGCOMM | 2004年 / 6卷
关键词
D O I
10.1039/b412700e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel zinc coordination supramolecular complex, {[Zn-3(OABDC)(2)(phen)(3)].2H2(O)}(n), with an open-ended nanotube architecture based on a nano-sized tetranuclear Zn-4(OABDC)(4) metallacycle repeating unit, is strategically designed and synthesized using a unique scorpion-shaped carboxylate ligand (5-oxyacetate isophthalic acid=H(3)OABDC) and phenanthroline.
引用
收藏
页码:315 / 317
页数:3
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