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Planar and central chiral [2.2]paracyclophanes as powerful catalysts for asymmetric 1,2-addition reactions

被引：86
作者：
Bräse, S
Dahmen, S
Höfener, S
Lauterwasser, F
Kreis, M
Ziegert, RE
机构：
[1] Univ Karlsruhe, Inst Organ Chem, D-76131 Karlsruhe, Germany
[2] Cynora GmbH, D-52134 Herzogenrath, Germany
[3] Univ Bonn, Kekule Inst Organ Chem & Biochem, D-53121 Bonn, Germany
来源：
SYNLETT | 2004年 / 15期
关键词：
asymmetric catalysis; ligands; paracyclophanes; zinc; nucleophilic additions;
D O I：
10.1055/s-2004-836029
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Planar and central chiral [2.2]paracyclophane ligands have been designed and used in the highly enantioselective addition of alkyl, alkenyl, alkynyl and aryl zinc reagents to aldehydes and imines.
引用
收藏
页码：2647 / 2669
页数：23
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