Azaporphyrins: Structure of the reaction centre and reactions of complex formation

被引：72

作者：

Stuzhin, PA

Khelevina, OG

机构：

[1] State Academy of Chemical Technology

来源：

COORDINATION CHEMISTRY REVIEWS | 1996年 / 147卷

关键词：

porphyrins; phthalocyanines; azaporphyrins; complex formation;

D O I：

10.1016/0010-8545(94)01126-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

X-ray, spectral (UV-visible, nuclear magnetic resonance and photoelectron spectroscopy) data and quantum-chemical calculation results for porphyrins, phthalocyanines and azaporphyrins are compared and conclusions about the influence of aza substitution on the geometry of CN skeleton and on the state of N-H bonds in porphyrin-type ligands are made. The studies of kinetics of metal ion incorporation in azaporphyrins are reviewed and the effect of the ligand structure, nature of metal salt and solvent on the complex formation reaction is discussed.

引用

页码：41 / 86

页数：46

共 125 条

[1]

ABRAHAM RJ, 1974, TETRAHEDRON LETT, P1183

[2]

Andronova N. A., 1974, Zhurnal Prikladnoi Spektroskopii, V20, P312

[3] PORPHYRINS .1. INTRAMOLECULAR HYDROGEN BONDING IN PYRROMETHENES AND PORPHYRINS [J].