Gas sensitivity of composite Langmuir-Blodgett films of Fe2O3 nanoparticle-copper phthalocyanine

被引:25
作者
Huo, LH
Li, XL
Li, W
Xi, SQ [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, Lab Rare Earth Chem & Phys, Changchun 130022, Peoples R China
[2] Heilongjiang Univ, Coll Chem & Chem Engn, Harbin 150080, Peoples R China
基金
中国国家自然科学基金;
关键词
ferric oxide; nanoparticulate LB film; copper phthalocyanine derivative; gas sensitivity;
D O I
10.1016/S0925-4005(00)00605-5
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The Langmuir-Blodgett (LB) composite films, ferric oxide nanoparticle composite with tris-(2,3-di-t-amylphenoxy)-(8-quinolinolinolyl) copper phthalocyanine (CuPcA(2)), were obtained by capped type and alternated type and characterized by X-ray photoelectron spectroscopy (XPS) and visible spectra. The gas sensitivity of the composite films and the pure ferric oxide and pure CuPcA(2) LB films to ammonia and ethanol were measured at room temperature. The composite films could be used as the C2H5OH sensors in the range of 2-8 or 100-200 ppm. The XPS data suggested that the adduct complex NH3-CuPcA(2) was formed after the capped film was exposed to the detected gas of ammonia. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:77 / 81
页数:5
相关论文
共 15 条
  • [1] Particulate multilayers prepared from surfactant-stabilized SnO2 nanoparticles
    Cao, LX
    Huo, LH
    Ping, GC
    Wang, DM
    Zeng, GF
    Xi, SQ
    [J]. THIN SOLID FILMS, 1999, 347 (1-2) : 258 - 262
  • [2] DING HM, 1996, CHEMISTRY, V11, P5
  • [3] H-2 SENSORS USING FE2O3-BASED THIN-FILM
    HARA, K
    NISHIDA, N
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 1994, 20 (2-3) : 181 - 186
  • [4] Preparation, structure, and properties of three-dimensional ordered α-Fe2O3 nanoparticulate film
    Huo, LH
    Li, W
    Lu, LH
    Cui, HN
    Xi, SQ
    Wang, J
    Zhao, B
    Shen, YC
    Lu, ZH
    [J]. CHEMISTRY OF MATERIALS, 2000, 12 (03) : 790 - 794
  • [5] NUCLEAR MAGNETIC RESONANCE SPECTRA AND ELECTRONIC SPECTRA OF SOME SILICON AND GERMANIUM PHTHALOCYANINES
    KANE, AR
    SULLIVAN, JF
    KENNY, DH
    KENNEY, ME
    [J]. INORGANIC CHEMISTRY, 1970, 9 (06) : 1445 - &
  • [6] Layer-by-layer assembly of ultrathin composite films from micron-sized graphite oxide sheets and polycations
    Kovtyukhova, NI
    Ollivier, PJ
    Martin, BR
    Mallouk, TE
    Chizhik, SA
    Buzaneva, EV
    Gorchinskiy, AD
    [J]. CHEMISTRY OF MATERIALS, 1999, 11 (03) : 771 - 778
  • [7] Preparation and organized assembly of nanoparticulate TiO2-stearate alternating Langmuir-Blodgett films
    Li, LS
    Hui, Z
    Chen, YM
    Zhang, XT
    Peng, XG
    Liu, ZF
    Li, TJ
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1997, 192 (02) : 275 - 280
  • [8] X-RAY PHOTOELECTRON SPECTROSCOPIC STUDIES OF IRON-OXIDES
    MCINTYRE, NS
    ZETARUK, DG
    [J]. ANALYTICAL CHEMISTRY, 1977, 49 (11) : 1521 - 1529
  • [9] PENG J, 1993, SENSOR ACTUAT B-CHEM, V13, P591
  • [10] FORMATION OF NANOPARTICULATE FE2O3-STEARATE MULTILAYER THROUGH THE LANGMUIR-BLODGETT METHOD
    PENG, XG
    ZHANG, Y
    YANG, J
    ZOU, BS
    XIAO, LZ
    LI, TJ
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (08) : 3412 - 3415