Detection of adulterations of honey with high fructose syrups from inulin by GC analysis

被引:71
作者
Ruiz-Matute, A. I. [1 ]
Rodriguez-Sanchez, S. [1 ]
Sanz, M. L. [1 ]
Martinez-Castro, I. [1 ]
机构
[1] CSIC, Inst Quim Organ Gen, E-28006 Madrid, Spain
关键词
Food adulteration; High fructose inulin syrup; Honey; Carbohydrates; Food processing fraud; Food analysis; Food composition; CHROMATOGRAPHY-MASS SPECTROMETRY; GAS-LIQUID CHROMATOGRAPHY; SUGAR SYRUPS; TRIMETHYLSILYL; SPECTROSCOPY; IDENTIFICATION; TRISACCHARIDES; CLASSIFICATION; DISACCHARIDES; QUANTITATION;
D O I
10.1016/j.jfca.2009.10.004
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A GC-MS method has been developed for the detection of honey adulteration with high fructose inulin syrups (HFIS). Carbohydrate composition of HFIS with different degrees of polymerization was studied; fructose, sucrose, dianhydrides of fructose (DFAs), inulobiose, kestoses and inulotriose were detected in all the samples. Honey adulterations with 5%, 10% and 20% of HFIS were performed. Inulotriose proved to be the best marker of honey adulteration with these syrups since it was not detected in any of the honey samples analyzed. (C) 2010 Elsevier Inc. All rights reserved.
引用
收藏
页码:273 / 276
页数:4
相关论文
共 19 条
[1]  
[Anonymous], 1970, Advances in Carbohydrate Chemistry and Biochemistry, DOI [DOI 10.1016/S0065-2318(08)60430-8, 10.1016/S0065-2318(08)60430-8]
[2]  
[Anonymous], 1996, FRUIT PROCESS
[3]  
*AOAC INT, 1999, 99812 AOAC INT
[4]  
BROBST KM, 1966, CEREAL CHEM, V43, P35
[5]   Characterization of O-trimethylsilyl oximes of trisaccharides by gas chromatography-mass spectrometry [J].
Brokl, Michal ;
Cristina Soria, Ana ;
Martinez-Castro, Isabel ;
Luz Sanz, Maria ;
Isabel Ruiz-Matute, Ana .
JOURNAL OF CHROMATOGRAPHY A, 2009, 1216 (22) :4689-4692
[6]   Characteristic fragmentation patterns of the trimethylsilyl and trimethylsilyl-oxime derivatives of various saccharides as obtained by gas chromatography coupled to ion-trap mass spectrometry [J].
Fuzfai, Zs. ;
Boldizsar, I. ;
Molnar-Perl, I. .
JOURNAL OF CHROMATOGRAPHY A, 2008, 1177 (01) :183-189
[7]   GAS-CHROMATOGRAPHIC ANALYSIS OF SUGARS IN GRANOLA CEREALS [J].
LI, BW ;
SCHUHMANN, PJ .
JOURNAL OF FOOD SCIENCE, 1981, 46 (02) :425-427
[8]   HPAEC-PAD oligosaccharide analysis to detect adulterations of honey with sugar syrups [J].
Morales, V. ;
Corzo, N. ;
Sanz, M. L. .
FOOD CHEMISTRY, 2008, 107 (02) :922-928
[9]   Discrimination and classification of beet and cane inverts in honey by FT-Raman spectroscopy [J].
Paradkar, MM ;
Irudayaraj, J .
FOOD CHEMISTRY, 2002, 76 (02) :231-239
[10]   Qualitative and quantitative evaluation of mono- and disaccharides in D-fructose, D-glucose and sucrose caramels by gas-liquid chromatography-mass spectrometry Di-D-fructose dianhydrides as tracers of caramel authenticity [J].
Ratsimba, V ;
Fernández, JMG ;
Defaye, J ;
Nigay, H ;
Voilley, A .
JOURNAL OF CHROMATOGRAPHY A, 1999, 844 (1-2) :283-293