Peculiar band gap structure of graphene nanoribbons

Graphene nanoribbons are quasi-one-dimensional meterials with finite width. Characterizing a wide class of nanoribbons by edge shape and width, we make a systematic analysis of their electronic properties. The band gap structure of nanoribbons is shown to exhibit a valley structure with stream-like sequences of metallic or almost metallic nanoribbons. Among them, all zigzag nanoribbons are metallic, and armchair nanoribbons are metallic by period of 3. We find that these stream-like sequences correspond to equi-width curves, and that the band gap of chiral and armchair nanoribbons oscillate as a function of the width. Furthermore a possible application of nanoribbons to nanoelectronics is discussed. (c) 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.