Aurophilicity-impaired internal molecular motion of trinuclear gold(I) complexes

被引:45
作者
Zank, J [1 ]
Schier, A [1 ]
Schmidbaur, H [1 ]
机构
[1] Tech Univ Munich, Inst Anorgan Chem, D-85747 Garching, Germany
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 03期
关键词
D O I
10.1039/a708704g
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The trinuclear (chloro)gold(I) complex of the tritertiary phosphine PhP[C6H4(PPh2)-2](2) was found to have a compact unsymmetrical structure in the crystalline state which is retained in solution owing to the fixation of the gold atoms through intermetallic contacts.
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收藏
页码:323 / 324
页数:2
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