Catalytic enantioselective 1,3-dipolar cycloaddition reactions of nitrones

被引：297

作者：

Gothelf, KV ^{[1
]}

Jorgensen, KA ^{[1
]}

机构：

[1] Aarhus Univ, Dept Chem, Ctr Met Catalyzed React, DK-8000 Aarhus C, Denmark

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 16期

关键词：

D O I：

10.1039/b004597g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The rapid developments in the field of catalytic enantioselective 1,3-dipolar cycloaddition reactions of nitrones which have occurred during the last six years are reported. A series of catalysts has been applied for both the normal electron-demand and inverse electron-demand 1,3-dipolar cycloaddition reaction of nitrones with electron-deficient and electron-rich alkenes, respectively. In several cases a high degree of control of both the diastereo- and enantioselectivity has been achieved.

引用

页码：1449 / 1458

页数：10

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