Anodic oxidation of 5-amino-1,4-naphthoquinone (ANQ) and synthesis of a conducting polymer (PANQ)

被引：38

作者：

Pham, MC

Piro, B

Bazzaoui, EA

Hedayatullah, M

Lacroix, JC

Novak, P

Haas, O

机构：

[1] Univ Paris 07, CNRS, URA 34, Inst Topol & Dynam Syst, F-75005 Paris, France

[2] Paul Scherrer Inst, Electrochem Sect, CH-5232 Villigen, Switzerland

来源：

SYNTHETIC METALS | 1998年 / 92卷 / 03期

关键词：

electrochemical polymerization; in situ IR spectroscopy; poly(5-amino-1,4-naphthoquinone); batteries;

D O I：

10.1016/S0379-6779(98)80087-8

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The electrooxidation of 5-amino-1,4-naphthoquinone (ANQ) at glassy carbon and Pt electrodes in acetonitrile leads to functionalized polymer films. Results from different spectroscopic techniques (FT-IR, UV-Vis, X-ray photoelectron spectroscopy (XPS)) and frontier orbital considerations converge to a definition of poly(5-amino-1,4-naphthoquinone) (PANQ) structure which is of the polyaniline-type bearing one quinone group per ANQ moiety. (C) 1998 Elsevier Science S.A.

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收藏

页码：197 / 205

页数：9

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