Methyl trifluoropyruvate diethoxyphosphorylimine

被引：10

作者：

Onys'ko, PP ^{[1
]}

Rassukanaya, YV ^{[1
]}

Sinitsa, AD ^{[1
]}

机构：

[1] Natl Acad Sci Ukraine, Inst Organ Chem, Kiev, Ukraine

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2002年 / 72卷 / 11期

关键词：

Alcohol; Methyl; Phenol; Indole; Trifluoropyruvate;

D O I：

10.1023/A:1023376826251

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first example of trifluoropyruvate phosphorylimines was prepared, and its capability for O- and S-amidoalkylation of water, alcohols, and compounds with the SH function was shown. Phenol and 4-methoxyphenol are O-alkylated, while 3-dimethylaminophenol and indole undergo regiospecific C-alkylation at the site of the highest pi-electron density.

引用

页码：1699 / 1702

页数：4

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