Styrenation of triglyceride oils by macromonomer technique

被引：23

作者：

Güner, FS ^{[1
]}

Usta, S ^{[1
]}

Erciyes, AT ^{[1
]}

Yagci, Y ^{[1
]}

机构：

[1] Istanbul Tech Univ, Dept Chem Engn, TR-80628 Istanbul, Turkey

来源：

JOURNAL OF COATINGS TECHNOLOGY | 2000年 / 72卷 / 907期

关键词：

D O I：

10.1007/BF02698030

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A novel macromer technique is described for the styrenation of triglyceride oils. Triglyceride oil-based macromers were prepared via successive transesterification ann condensation reactions. The macromers were styrenated at 100 degrees C using benzoyl peroxide as an initiator. The styrenation led to improved film properties with semidrying oils. Homopolymerization of the macromonomers failed due to the stearic hindrance of the bulky oil moieties. The results obtained were also evaluated by considering the degree of unsaturation.

引用

页码：107 / 110

页数：4

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