Ion pairing and counterion condensation in aqueous electrolyte and polyelectrolyte solutions: Insights from molecular simulation

被引：14

作者：

Chialvo, Ariel A. ^{[1
]}

Simonson, J. Michael ^{[1
]}

机构：

[1] Oak Ridge Natl Lab, Div Chem Sci, Aqueous Chem & Geochem Grp, Oak Ridge, TN 37831 USA

来源：

JOURNAL OF MOLECULAR LIQUIDS | 2007年 / 134卷 / 1-3期

关键词：

counterion condensation; ion pairing; polyelectrolytes; molecular dynamics simulation;

D O I：

10.1016/j.molliq.2006.12.017

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We discuss the molecular-based study of ion-pair formation in LiCl aqueous solutions and its implications on the interpretation of the raw data from neutron diffraction with isotopic substitution experiments, the counterion condensation in aqueous polyelectrolyte solutions comprising short-chain lithium poly-styrene sulfonate (L+-PSS-), as well as their interplay leading to the occurrence of "like-charge" attractive interactions in the presence of salts of polyvalent counterions. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：15 / 22

页数：8

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