Development of a 100 W rechargeable bipolar zinc/oxygen battery

被引：39

作者：

Muller, S ^{[1
]}

Haas, O

Schlatter, C

Comninellis, C

机构：

[1] Paul Scherrer Inst, CH-5232 Villigen PSI, Switzerland

[2] Swiss Fed Inst Technol, CH-1015 Lausanne, Switzerland

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 1998年 / 28卷 / 03期

关键词：

bipolar zinc/oxygen battery; zinc plated copper foam; bifunctional oxygen electrode;

D O I：

10.1023/A:1003267700824

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A bipolar filter press-type electrically rechargeable Zn/O-2 battery has been developed. Reticulated copper foam served as substrate for the zinc deposit on the anodic side, and La0.6Ca0.4CoO3-catalysed bifunctional oxygen electrodes were used on the cathodic side of the cells. The 100 cm(2) unit cell had an open circuit voltage of 1.4V (O-2) in moderately alkaline electrolyte. The open circuit voltage and the peak power measured for a stack containing seven cells were similar to 10 V and similar to 90 W, respectively. The current-potential behaviour was determined as a function of the number of bipolar cells, and the maximum discharge capacity was determined at different discharge rates.

引用

页码：305 / 310

页数：6

共 13 条

[1] LOW-ZINC-SOLUBILITY ELECTROLYTES FOR USE IN ZINC NICKEL-OXIDE CELLS [J].