Creation of polar and nonpolar ultra-long-range Rydberg molecules

被引:373
作者
Greene, CH [1 ]
Dickinson, AS
Sadeghpour, HR
机构
[1] Univ Colorado, Dept Phys, Boulder, CO 80309 USA
[2] Univ Colorado, JILA, Boulder, CO 80309 USA
[3] Harvard Smithsonian Ctr Astrophys, Inst Theoret Atom & Mol Phys, Cambridge, MA 02138 USA
[4] Univ Newcastle Upon Tyne, Dept Phys, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England
关键词
D O I
10.1103/PhysRevLett.85.2458
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We predict the existence of a ubiquitous class of long-range molecular Rydberg states, whose Born-Oppenheimer potential curves are oscillatory in nature. These oscillations reflect the nodal structure of the atomic Rydberg state wave functions. The temperature and density of atoms in a Bose-Einstein condensate an particularly favorable for the laser excitation of ultra-long-range vibrational bound states localized at internuclear distances in the range 10(3)-10(5) a.u. A surprising trilobitelike class of polar homonuclear diatomics should exhibit electric dipole moments in the kilodebye range.
引用
收藏
页码:2458 / 2461
页数:4
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