Excited-state intramolecular proton transfer via a preexisting hydrogen bond in semirigid polyquinoline

被引：39

作者：

Chang, DW

Kim, S

Park, SY ^{[1
]}

Yu, H

Jang, DJ

机构：

[1] Seoul Natl Univ, Dept Fiber & Polymer Sci, Seoul 151742, South Korea

[2] Seoul Natl Univ, Sch Chem, Seoul 151742, South Korea

来源：

MACROMOLECULES | 2000年 / 33卷 / 20期

关键词：

D O I：

10.1021/ma000126g

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The semirigid prototype polyquinoline (PQH) was synthesized with alternating building blocks, one of which has an intramolecular hydrogen bond. The excited-state intramolecular proton transfer (ESIPT) of the polymer was examined. Results revealed that the PQH films experienced ESIPT and electronic arrangement in the shorter times of 8 and 20 ps, in both photoluminescence and electroluminescence measurements.

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页码：7223 / 7225

页数：3

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